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Set Account As Default In Outlook For. Do a final Outlook restart. If the value is set to 1 new messages will have the default account set as the sending account.
To set up the default account select File Account Settings and then select Account Settings from the dropdown menu. Enter your email address or signin name. It shows you a list of all your accounts.
Go to Settings View all Outlook settings Compose and reply.
Go to the File tab. A list of your accounts is in the left pane of. On the Select Folders dialog box all your accounts are listed with their respective folders under them. That said chances are that you might want customize the look and feel of their Outlook messages.